#BRUKER APEX 3 MANUAL SOFTWARE#
#BRUKER APEX 3 MANUAL WINDOWS#

Gili, P.: Structure and properties of Cu (II)(o-hydroxypropiophenone-salicylhydrazide) (2, 2вЂІ-bipyridyl) and Cu (II)(o-hydroxypropiophenone-salicylhydrazide)(2, 2вЂІ-bipyridylamine) monohydrate H 2O. M.: Three-level synthetic strategy towards mixed valence and hheterometallic Gridlike Arrays. SHELXL Reference Manual, version 5.1 Bruker analytical X-ray systems: Madison, WI (1997).

#BRUKER APEX 3 MANUAL SOFTWARE#

M.: SADABS, A software for empirical absorption correction University of GГ¶ttingen: GГ¶ttingen, Germany (1997).

#BRUKER APEX 3 MANUAL WINDOWS#

SMART and SAINT for Windows NT Software Reference Manuals, Version 5.0, Bruker Analytical X-Ray Systems, Madison, WI (1997). The authors gratefully acknowledge Scientific and technological project of Henan province (192102310232), the Anyang Key Laboratory for Chemical Biosensing (21302003), Key discipline of environmental engineer of Anyang Institute of Technology. The Cu atom is in a slightly distorted square coordination environment, with two oxygen atoms and one nitrogen atom from the chelate ligand, one nitrogen atom from the pyridine molecule. The complex consists of one ligand, one pyridine molecule and one Cu atom. The Schiff base ligand has been synthesized by our group. The metal complexes of such Schiff bases have several applications in biological probes, DNA cleaving agents, catalysts, sensing matrials and corrosion inhibitors. Aroylhydrazone Schiff bases are one type of a polydentate ligand, which are known for a variety of molecular architectures and coordination polyhedra. Polydentate Schiff base ligands are important for the development of the coordination chemistry.

The N-bound H atoms were located in a difference Fourier map but were refined with a distance restraint of N-H = 0.88 В± 0.01 Г…, and with U iso(H) set to 1.2 U equiv(N). The C-bound H atoms were geometrically placed (C-H = 0.95вЂ“0.98 Г…) and refined as riding with U iso(H) = 1.2вЂ“1.5 U eq(C). After a few days, colourless block crystals formed. The mixture was filtered, and left at room temperature. AtomДў-Hydroxy-4-methoxybenzaldehyde 5-chlorosalicylhydrazide (0.32 g, 1 mmol) in 10 mL methanol and 1 mL pyridine was stirred at room temperature for 1 h. Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Г… 2).

Bruker apex 3 manual